請(qǐng)高手幫忙翻譯一下 3

Huliaishang 2018-11-22 17:49:22 262  瀏覽

• 2.2.1. Physical and physicochemical characterization The particle size distribution of the Ch-zeolite was determined using a laser diffraction equipment (CILASk 1064) and standard wet sieving (Mesh Tylerk series). Scanning electron mic... 2.2.1. Physical and physicochemical characterization The particle size distribution of the Ch-zeolite was determined using a laser diffraction equipment (CILASk 1064) and standard wet sieving (Mesh Tylerk series). Scanning electron microscopy (SEM-PHILIPSk XL20) was used for photomicrographs as well as to analyse the Ch-zeolite composition (Energy Dispersion X-ray， EDX). The sample was initially placed in a vacuum chamber for coating with a thin layer (few nanometers) of gold (Au). The specific surface area of the material was measured by the methylene blue technique and by nitrogen gas adsorption methods， with the latter also providing information about particle porosity. In the methylene blue adsorption method， aqueous solutions (50 ml) of methylene blue (100 mg l 1) were agitated using an orbital shaker (Marconik) for an hour at room temperature in the presence of different quantities of the Ch-zeolite (0.05–0.3 g). The suspensions were then allowed to settle for 23 h and the resulting supernatants were centrifuged at 5000 rpm before the analysis of the residual methylene blue concentration. Results obtained correspond to averaged values of three different experiments. The specific surface area was evaluated by the Langmuir model， assuming the formation， at high concentrations， of a dye monolayer and 1.08 nm2 molecule 1， for the cross-sectional area (Van den Hul and Lyklema， 1968). The Ch-zeolite specific surface area was evaluated by the nitrogen gas adsorption method， using automated equipment (Autosorb 1-Quantachrome Instrumentsk)， employing multipoint BET isotherm adsorption data fitting. Also from these data， the porosity of the material was evaluated through parameters such as volume of total pores (d < 206 nm)， surface area and volume of micropores (d < 2 nm; Micropore Analysis Method). Zeta potential measurements for the natural and ammonia loaded zeolite， as a function of medium pH， were determined using a Zeta Plusk equipment (Brookhaven Instruments). Suspensions (0.01% v/v) of the Ch-zeolite， previously sieved below 37 Am (400 Mesh Tylerk)， in a 10 3 mol l 1 solution of KNO3 were used and the medium pH was controlled with the addition of HNO3 (pH< 7) and KOH (pH>7)， separately. For the Ch-zeolite saturated with ammonia， suspensions of the material were prepared by the same procedure， except that the sample was loaded with 100 mg NH3–N l 1 of ammonia. 展開(kāi)